opensmile
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Subchunk1Size: 12smilePcm: bogus wave/riff header or file in wrong format
smilePcm: Riff: 46464952 Format: 45564157 Subchunk1ID: 20746d66 Subchunk2ID: 61640000 AudioFormat: 1 Subchunk1Size: 12smilePcm: bogus wave/riff header or file in wrong format ('D:\Projects\Audio\Emotion\SER\AcousticFeatureExtraction\audios/EP03_seq04_sc132.wav')! (maybe you are trying to read a 32-bit wave file which is not yet supported (new header type...)?)
The Wave file parser in openSMILE only supports a subset of all possible formats. I suggest to open the file in another software and re-export it as 16-bit signed integer little-endian. You may also want to try with the recently released version 3.0, it might be that this particular incompatibility is already fixed there.