opsin
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6-chloro-7-deazapurine
Opsin gives ClC1=C2CC=NC2=NC=N1 for 6-chloro-7-deazapurine
I would expect ClC1=C2C=CNC2=NC=N1
i.e., that an H migrates to the other N in the 5-membered ring, rather than stay on transmuted C