Use full path to Cylc when submitting jobs

[ScottWales]

Use the full path to the Cylc script when submitting jobs

Fixes #6301

Check List

• [x] I have read CONTRIBUTING.md and added my name as a Code Contributor.
• [x] Contains logically grouped changes (else tidy your branch by rebase).
• [x] Does not contain off-topic changes (use other PRs for other changes).
• [x] Applied any dependency changes to both setup.cfg (and conda-environment.yml if present).
• [x] Tests are included (or explain why tests are not needed).
• [x] Changelog entry included if this is a change that can affect users
• [ ] Cylc-Doc pull request opened if required at cylc/cylc-doc/pull/XXXX.
• [ ] If this is a bug fix, PR should be raised against the relevant ?.?.x branch.